Thermodynamic perturbation theory for associating fluids confined in a one-dimensional pore
نویسندگان
چکیده
منابع مشابه
Thermodynamic perturbation theory for associating fluids confined in a one-dimensional pore.
In this paper, a new theory is developed for the self-assembly of associating molecules confined to a single spatial dimension, but allowed to explore all orientation angles. The interplay of the anisotropy of the pair potential and the low dimensional space results in orientationally ordered associated clusters. This local order enhances association due to a decrease in orientational entropy. ...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2015
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.4922547